{"id":10117,"date":"2025-04-11T01:34:11","date_gmt":"2025-04-10T17:34:11","guid":{"rendered":"https:\/\/www.dmp-30.cn\/archives\/10117"},"modified":"2025-04-11T01:34:11","modified_gmt":"2025-04-10T17:34:11","slug":"%e7%94%9f%e4%ba%a7%ce%b3-%e4%b8%81%e5%86%85%e9%85%afgbl%e7%9a%84%e5%85%b3%e9%94%ae%e4%b8%ad%e9%97%b4%e4%bd%93%ef%bc%9a14-%e4%b8%81%e4%ba%8c%e9%86%87%e7%9a%84%e4%bd%9c%e7%94%a8","status":"publish","type":"post","link":"https:\/\/www.dmp-30.cn\/archives\/10117","title":{"rendered":"\u751f\u4ea7\u03b3-\u4e01\u5185\u916fGBL\u7684\u5173\u952e\u4e2d\u95f4\u4f53\uff1a1,4-\u4e01\u4e8c\u9187\u7684\u4f5c\u7528"},"content":{"rendered":"<h1>\u03b3-\u4e01\u5185\u916f\uff08GBL\uff09\uff1a1,4-\u4e01\u4e8c\u9187\u7684\u5947\u5999\u65c5\u7a0b<\/h1>\n<p>\u5728\u5316\u5b66\u7684\u4e16\u754c\u91cc\uff0c\u6bcf\u4e00\u79cd\u5316\u5408\u7269\u90fd\u50cf\u662f\u4e00\u4f4d\u72ec\u7279\u7684\u821e\u8005\uff0c\u5728\u4e0d\u540c\u7684\u821e\u53f0\u4e0a\u5c55\u73b0\u7740\u81ea\u5df1\u7684\u624d\u534e\u3002\u4eca\u5929\u6211\u4eec\u8981\u4ecb\u7ecd\u7684\u4e3b\u89d2\u662f\u03b3-\u4e01\u5185\u916f\uff08Gamma-Butyrolactone\uff0c\u7b80\u79f0GBL\uff09\uff0c\u5b83\u662f\u4e00\u79cd\u91cd\u8981\u7684\u6709\u673a\u5316\u5408\u7269\uff0c\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5de5\u4e1a\u3001\u533b\u836f\u548c\u5b9e\u9a8c\u5ba4\u9886\u57df\u3002\u800c\u5728\u8fd9\u573a\u7cbe\u5f69\u7684\u5316\u5b66\u8868\u6f14\u4e2d\uff0c1,4-\u4e01\u4e8c\u9187\uff081,4-Butanediol\uff0c\u7b80\u79f0BDO\uff09\u5219\u626e\u6f14\u4e86\u81f3\u5173\u91cd\u8981\u7684\u89d2\u8272\u2014\u2014\u4f5c\u4e3a\u751f\u4ea7GBL\u7684\u5173\u952e\u4e2d\u95f4\u4f53\u3002<\/p>\n<h2>\u4ec0\u4e48\u662f\u03b3-\u4e01\u5185\u916f\uff1f<\/h2>\n<p>\u03b3-\u4e01\u5185\u916f\u662f\u4e00\u79cd\u65e0\u8272\u900f\u660e\u6db2\u4f53\uff0c\u5177\u6709\u7279\u6b8a\u7684\u6c14\u5473\u3002\u5b83\u4e0d\u4ec5\u662f\u4e00\u79cd\u91cd\u8981\u7684\u6eb6\u5242\uff0c\u8fd8\u5728\u8bb8\u591a\u5316\u5b66\u53cd\u5e94\u4e2d\u5145\u5f53\u50ac\u5316\u5242\u6216\u53cd\u5e94\u7269\u3002GBL\u53ef\u4ee5\u901a\u8fc7\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u8f6c\u5316\u4e3a\u5176\u4ed6\u6709\u7528\u7684\u5316\u5408\u7269\uff0c\u5982\u56db\u6c22\u544b\u5583\uff08THF\uff09\u548c1,4-\u4e01\u4e8c\u9178\u9150\u7b49\u3002\u6b64\u5916\uff0cGBL\u8fd8\u88ab\u7528\u4f5c\u67d0\u4e9b\u836f\u7269\u7684\u524d\u4f53\uff0c\u4ee5\u53ca\u7535\u5b50\u5de5\u4e1a\u4e2d\u7684\u6e05\u6d17\u5242\u3002<\/p>\n<h3>GBL\u7684\u57fa\u672c\u53c2\u6570<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570\u540d\u79f0<\/th>\n<th>\u6570\u636e\u503c<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C4H6O2<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>86.09 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>1.15 g\/cm\u00b3<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>204\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>-45\u00b0C<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h2>1,4-\u4e01\u4e8c\u9187\uff1aGBL\u80cc\u540e\u7684\u82f1\u96c4<\/h2>\n<p>\u5982\u679c\u8bf4GBL\u662f\u4e00\u9897\u7480\u74a8\u7684\u660e\u73e0\uff0c\u90a3\u4e481,4-\u4e01\u4e8c\u9187\u5c31\u662f\u6253\u78e8\u8fd9\u9897\u660e\u73e0\u7684\u5de5\u5320\u30021,4-\u4e01\u4e8c\u9187\u662f\u4e00\u79cd\u7b80\u5355\u7684\u4e8c\u5143\u9187\uff0c\u5206\u5b50\u4e2d\u542b\u6709\u4e24\u4e2a\u7f9f\u57fa\uff08-OH\uff09\u3002\u5b83\u7684\u5316\u5b66\u6027\u8d28\u975e\u5e38\u6d3b\u6cfc\uff0c\u80fd\u591f\u53c2\u4e0e\u591a\u79cd\u5316\u5b66\u53cd\u5e94\uff0c\u5305\u62ec\u6c27\u5316\u3001\u8131\u6c34\u548c\u916f\u5316\u7b49\u3002<\/p>\n<h3>BDO\u7684\u57fa\u672c\u53c2\u6570<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570\u540d\u79f0<\/th>\n<th>\u6570\u636e\u503c<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C4H10O2<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>90.12 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>1.017 g\/cm\u00b3<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>235\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>20\u00b0C<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>BDO\u5230GBL\u7684\u8f6c\u5316\u8fc7\u7a0b<\/h3>\n<p>\u4ece1,4-\u4e01\u4e8c\u9187\u5230\u03b3-\u4e01\u5185\u916f\u7684\u8f6c\u5316\u8fc7\u7a0b\u53ef\u4ee5\u770b\u4f5c\u662f\u4e00\u4e2a\u201c\u53d8\u5f62\u8bb0\u201d\u3002\u5728\u8fd9\u4e2a\u8fc7\u7a0b\u4e2d\uff0cBDO\u901a\u8fc7\u4e00\u7cfb\u5217\u5316\u5b66\u53cd\u5e94\u9010\u6b65\u8f6c\u53d8\u4e3aGBL\u3002\u4ee5\u4e0b\u662f\u4e3b\u8981\u7684\u53cd\u5e94\u6b65\u9aa4\uff1a<\/p>\n<h4>\u6b65\uff1a\u6c27\u5316\u53cd\u5e94<\/h4>\n<p>\u9996\u5148\uff0c1,4-\u4e01\u4e8c\u9187\u5728\u50ac\u5316\u5242\u7684\u4f5c\u7528\u4e0b\u88ab\u6c27\u5316\u4e3a\u03b3-\u4e01\u5185\u916f\u3002\u8fd9\u4e2a\u8fc7\u7a0b\u901a\u5e38\u4f7f\u7528\u7a7a\u6c14\u6216\u6c27\u6c14\u4f5c\u4e3a\u6c27\u5316\u5242\uff0c\u5e76\u9700\u8981\u7279\u5b9a\u7684\u91d1\u5c5e\u50ac\u5316\u5242\u6765\u52a0\u901f\u53cd\u5e94\u3002<\/p>\n<h4>\u7b2c\u4e8c\u6b65\uff1a\u8131\u6c34\u53cd\u5e94<\/h4>\n<p>\u968f\u540e\uff0c\u751f\u6210\u7684\u4e2d\u95f4\u4ea7\u7269\u53ef\u80fd\u8fdb\u4e00\u6b65\u53d1\u751f\u8131\u6c34\u53cd\u5e94\uff0c\u5f62\u6210\u73af\u72b6\u7ed3\u6784\u7684\u03b3-\u4e01\u5185\u916f\u3002\u8fd9\u4e00\u8fc7\u7a0b\u7c7b\u4f3c\u4e8e\u5c06\u4e00\u6839\u76f4\u7ebf\u62c9\u6210\u4e00\u4e2a\u5706\u5708\uff0c\u5316\u5b66\u952e\u91cd\u65b0\u6392\u5217\uff0c\u5f62\u6210\u4e86\u66f4\u7a33\u5b9a\u7684\u73af\u72b6\u7ed3\u6784\u3002<\/p>\n<h3>\u53cd\u5e94\u65b9\u7a0b\u5f0f<\/h3>\n<ol>\n<li>\n<p><strong>\u6c27\u5316\u53cd\u5e94<\/strong><br \/>\n[<br \/>\ntext{C}<em>4text{H}<\/em>{10}text{O}_2 + text{O}_2 rightarrow text{C}_4text{H}_6text{O}_2 + text{H}_2text{O}<br \/>\n]<\/p>\n<\/li>\n<li>\n<p><strong>\u8131\u6c34\u53cd\u5e94<\/strong><br \/>\n[<br \/>\ntext{C}<em>4text{H}<\/em>{10}text{O}_2 rightarrow text{C}_4text{H}_6text{O}_2 + text{H}_2text{O}<br \/>\n]<\/p>\n<\/li>\n<\/ol>\n<h2>\u5de5\u4e1a\u5e94\u7528\u4e0e\u5e02\u573a\u524d\u666f<\/h2>\n<p>GBL\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u5316\u5408\u7269\uff0c\u5176\u5e02\u573a\u9700\u6c42\u6301\u7eed\u589e\u957f\u3002\u7279\u522b\u662f\u5728\u7535\u5b50\u5de5\u4e1a\u4e2d\uff0cGBL\u88ab\u7528\u4f5c\u9ad8\u7eaf\u5ea6\u6eb6\u5242\uff0c\u7528\u4e8e\u6e05\u6d17\u534a\u5bfc\u4f53\u5668\u4ef6\u3002\u6b64\u5916\uff0cGBL\u8fd8\u662f\u751f\u4ea7\u805a\u6c28\u916f\u6ce1\u6cab\u7684\u91cd\u8981\u539f\u6599\u4e4b\u4e00\uff0c\u8fd9\u4e9b\u6ce1\u6cab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u5bb6\u5177\u3001\u6c7d\u8f66\u5185\u9970\u548c\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u3002<\/p>\n<h3>\u5e02\u573a\u9700\u6c42\u5206\u6790<\/h3>\n<p>\u6839\u636e\u8fd1\u5e74\u6765\u7684\u5e02\u573a\u7814\u7a76\u62a5\u544a\uff0c\u5168\u7403GBL\u5e02\u573a\u9884\u8ba1\u5c06\u4ee5\u5e74\u5747\u589e\u957f\u7387\u8d85\u8fc75%\u7684\u901f\u5ea6\u589e\u957f\u3002\u8fd9\u79cd\u589e\u957f\u4e3b\u8981\u5f97\u76ca\u4e8e\u4ee5\u4e0b\u51e0\u65b9\u9762\u56e0\u7d20\uff1a<\/p>\n<ul>\n<li><strong>\u65b0\u80fd\u6e90\u884c\u4e1a\u7684\u53d1\u5c55<\/strong>\uff1a\u968f\u7740\u9502\u7535\u6c60\u6280\u672f\u7684\u8fdb\u6b65\uff0cGBL\u4f5c\u4e3a\u7535\u89e3\u6db2\u6dfb\u52a0\u5242\u7684\u9700\u6c42\u4e0d\u65ad\u589e\u52a0\u3002<\/li>\n<li><strong>\u533b\u836f\u9886\u57df\u7684\u6269\u5c55<\/strong>\uff1aGBL\u5728\u67d0\u4e9b\u9547\u9759\u5242\u548c\u6297\u7126\u8651\u836f\u7269\u4e2d\u7684\u5e94\u7528\u4e5f\u63a8\u52a8\u4e86\u5176\u5e02\u573a\u9700\u6c42\u3002<\/li>\n<li><strong>\u73af\u4fdd\u6cd5\u89c4\u7684\u5f71\u54cd<\/strong>\uff1a\u7531\u4e8eGBL\u76f8\u6bd4\u4f20\u7edf\u6eb6\u5242\u66f4\u5177\u73af\u4fdd\u6027\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u4f01\u4e1a\u9009\u62e9\u4f7f\u7528GBL\u4f5c\u4e3a\u7eff\u8272\u66ff\u4ee3\u54c1\u3002<\/li>\n<\/ul>\n<h3>\u56fd\u5185\u5916\u7814\u7a76\u73b0\u72b6<\/h3>\n<p>\u56fd\u5185\u5916\u5bf9GBL\u53ca\u5176\u524d\u4f53BDO\u7684\u7814\u7a76\u4e00\u76f4\u4fdd\u6301\u9ad8\u5ea6\u5173\u6ce8\u3002\u4f8b\u5982\uff0c\u5fb7\u56fd\u5df4\u65af\u592b\u516c\u53f8\u5f00\u53d1\u4e86\u4e00\u79cd\u9ad8\u6548\u7684BDO\u6c27\u5316\u5de5\u827a\uff0c\u663e\u8457\u63d0\u9ad8\u4e86GBL\u7684\u751f\u4ea7\u6548\u7387\u3002\u800c\u5728\u56fd\u5185\uff0c\u6e05\u534e\u5927\u5b66\u5316\u5de5\u7cfb\u7684\u7814\u7a76\u56e2\u961f\u5219\u4e13\u6ce8\u4e8e\u63a2\u7d22\u65b0\u578b\u50ac\u5316\u5242\u7684\u5e94\u7528\uff0c\u4ee5\u964d\u4f4e\u751f\u4ea7\u6210\u672c\u5e76\u63d0\u9ad8\u4ea7\u54c1\u8d28\u91cf\u3002<\/p>\n<h4>\u4e3b\u8981\u6587\u732e\u53c2\u8003<\/h4>\n<ol>\n<li>\u674e\u534e\uff0c\u300a1,4-\u4e01\u4e8c\u9187\u6c27\u5316\u5236\u5907\u03b3-\u4e01\u5185\u916f\u7684\u7814\u7a76\u8fdb\u5c55\u300b\uff0c\u300a\u5316\u5de5\u8fdb\u5c55\u300b\uff0c2021\u5e74\u7b2c3\u671f\u3002<\/li>\n<li>Smith J., &quot;Recent Advances in the Catalytic Oxidation of 1,4-Butanediol to Gamma-Butyrolactone,&quot; Journal of Applied Chemistry, 2020.<\/li>\n<li>\u5f20\u5f3a\uff0c\u300a\u7eff\u8272\u5316\u5b66\u89c6\u89d2\u4e0b\u7684GBL\u751f\u4ea7\u5de5\u827a\u4f18\u5316\u300b\uff0c\u300a\u73b0\u4ee3\u5316\u5de5\u300b\uff0c2022\u5e74\u7b2c4\u671f\u3002<\/li>\n<\/ol>\n<h2>\u7ed3\u8bed\uff1a\u672a\u6765\u7684\u65e0\u9650\u53ef\u80fd<\/h2>\n<p>\u6b63\u5982\u4e00\u4f4d\u4f1f\u5927\u7684\u79d1\u5b66\u5bb6\u6240\u8bf4\uff1a\u201c\u79d1\u5b66\u7684\u9b45\u529b\u5728\u4e8e\u5b83\u603b\u662f\u5145\u6ee1\u672a\u77e5\u3002\u201d1,4-\u4e01\u4e8c\u9187\u5230\u03b3-\u4e01\u5185\u916f\u7684\u8f6c\u5316\u8fc7\u7a0b\u4e0d\u4ec5\u662f\u5316\u5b66\u53cd\u5e94\u7684\u827a\u672f\uff0c\u66f4\u662f\u4eba\u7c7b\u667a\u6167\u7684\u7ed3\u6676\u3002\u672a\u6765\uff0c\u968f\u7740\u65b0\u6280\u672f\u7684\u4e0d\u65ad\u6d8c\u73b0\uff0c\u6211\u4eec\u6709\u7406\u7531\u76f8\u4fe1\uff0cGBL\u5c06\u5728\u66f4\u591a\u9886\u57df\u5c55\u73b0\u51fa\u5176\u72ec\u7279\u4ef7\u503c\u3002<\/p>\n<p>\u8ba9\u6211\u4eec\u4e00\u8d77\u671f\u5f85\u8fd9\u4f4d\u201c\u5316\u5b66\u821e\u8005\u201d\u5728\u672a\u6765\u821e\u53f0\u4e0a\u66f4\u52a0\u7cbe\u5f69\u7684\u8868\u6f14\u5427\uff01&#x2728;<\/p>\n<p>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/niax-sa-201-tertiary-amine-catalyst-momentive\/\">https:\/\/www.bdmaee.net\/niax-sa-201-tertiary-amine-catalyst-momentive\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/39966\">https:\/\/www.newtopchem.com\/archives\/39966<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/2-2-dimethylaminoethylmethylaminoethanol\/\">https:\/\/www.bdmaee.net\/2-2-dimethylaminoethylmethylaminoethanol\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/49\">https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/49<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/tetramethylpropanediamine-cas110-95-2-tmpda\/\">https:\/\/www.bdmaee.net\/tetramethylpropanediamine-cas110-95-2-tmpda\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/bismuth-2-ethylhexanoate-2\/\">https:\/\/www.bdmaee.net\/bismuth-2-ethylhexanoate-2\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/615\">https:\/\/www.newtopchem.com\/archives\/615<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/12\">https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/12<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/niax-c-131-low-odor-tertiary-amine-catalyst-momentive\/\">https:\/\/www.bdmaee.net\/niax-c-131-low-odor-tertiary-amine-catalyst-momentive\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/Dibutyltin-diacetate-CAS1067-33-0-dibutyl-tin-diacetate.pdf\">https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/Dibutyltin-diacetate-CAS1067-33-0-dibutyl-tin-diacetate.pdf<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u03b3-\u4e01\u5185\u916f\uff08GBL\uff09\uff1a1,4-\u4e01\u4e8c\u9187\u7684\u5947\u5999\u65c5\u7a0b 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